MATERIAL SAFETY DATA SHEET (Side-A & Side-B)

FLEXSET Side-A
SECTION I - MANUFACTURER IDENTIFICATION
MANUFACTURER’S NAME: Roklin Systems, Inc. ADDRESS: 20541 Pascal Way, Lake Forest, CA 92630 INFORMATION PHONE: 949-707-6111 EMERGENCY CONTACT: 949-707-6111 DATE REVISED: December 1st. 2008

SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS

BOILING POINT: >424°C (>693°F) SPECIFIC GRAVITY: (H2O=1): 1.01
VAPOR DENSITY: Heavier than air EVAPORATION RATE: .0000006 Pa at 20°C
SOLUBILITY IN WATER: Reacts with water APPEARANCE & ODOR: Amber Liquid, odorless

SECTION IV - FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: 200°C (442°F) METHOD USED: PMCC

FLAMMABLE LIMITS IN AIR BY VOLUME: Lower: N/E Upper: N/E

EXTINGUISHING MEDIA: Dry chemical, foam, carbon dioxide, avoid use of water.

SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved self contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), goggles, and full protective clothing are also required. Excessive pressure or temperature may cause explosive rupture of containers.

UNUSUAL FIRE AND EXPLOSION HAZARDS: Water contamination will produce carbon dioxide. Do not reseal contaminated containers as pressure buildup may rupture them.

SECTION V - REACTIVITY DATA

STABILITY: Stable under normal conditions.

CONDITIONS TO AVOID: Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause liberation of carbon dioxide and buildup of pressure.

INCOMPATIBILITY (MATERIALS TO AVOID): This product will react with any material containing active hydrogens, such as water, alcohol, ammonia, amines, alkalis and acids, the reaction with water is very slow under 50°C, but is accelerated at higher temperature and in the presence of alkalis, tertiary amines, and metal compounds. Some reactions can be violent. Keep away from strong oxidizers such as hydrogen peroxide, bromine and chronic acid.

HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Combustion products: carbon dioxide, carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, trace amounts of hydrogen cyanide and unidentified organic compounds.

HAZARDOUS POLYMERIZATION:May occur at high temperatures, above 204°C (400°F). Possible evolution of carbon dioxide gas at extremely high temperatures, may rupture closed containers.

SECTION VI - HEALTH HAZARD DATA

SKIN CONTACT:Isocyanates react with skin protein and moisture and can cause irritation. Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and, in some cases, skin sensitization. Individuals who have developed a skin sensitization can develop these symptoms as a result of contact with very small amounts of liquid material or as a result of exposure to vapor. Animal tests have indicated that respiratory sensitization can result from skin contact with MDI. This reinforces the need to prevent direct skin contact with the product by using Nitrile gloves, Tyvek suit and full face shield.

EYE CONTACT:Liquid, aerosols or vapors are severely irritating and can cause pain, tearing, reddening and swelling. Prolonged vapor contact may cause conjunctivitis. Any level of contact should not be left untreated.

SKIN ABSORPTION: Systemically toxic concentrations of this product will probably not be absorbed through human skin.

INGESTION:Can result in irritating and corrosive action in the mouth, stomach tissue and digestive tract. Symptoms can include sore throat, abdominal pain, nausea, vomiting and diarrhea.

INHALATION: The following information applies only to products that contain MDI that are applied by spraying or that require heating. Roklin products are neither heated nor sprayed and are below the TLV when used properly. MDI vapors or mist at concentrations above the TLV (Threshold Limit Value) can irritate (burning sensation) the mucous membranes in the respiratory tract (nose, throat, lungs) causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced lung function (breathing obstruction). High vapor concentrations may cause central nervous system (CNS) depression as evidenced by giddiness, headache, dizziness, and nausea. Persons with a preexisting, non-specific bronchial hyperactivity can respond to concentrations below the TLV with similar symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis, bronchial spasm and pulmonary edema (fluid in lungs). As a result of previous repeated overexposures or a single large dose, certain individuals may develop isocyanate sensitization (chemical asthma) which will cause them to react to a later exposure to isocyanate at levels well below the TLV. Similar to many non-specific asthmatic responses, there are reports that once sensitized an individual can experience these symptoms upon exposure to dust, cold air or other irritants. This increased lung sensitivity can persist for weeks and in severe cases for several years. Chronic overexposure to isocyanate has also been reported to cause lung damage (including decrease in lung function) which may be permanent. Sensitization can either be temporary or permanent.

HEALTH HAZARDS: ACUTE:Exposure may cause mucous membrane and respiratory tract irritation, tightness of chest, headache, shortness of breath, and a dry cough. At concentrations exceeding current occupational limits and for sensitized individuals at levels less than or greater than current occupational limits, asthma-like symptoms may occur. These symptoms may include coughing, wheezing, and shortness of breath. A hypersensitive pneumonitis may also occur if the person is sensitized. This syndrome is characterized by fever, nonproductive cough, wheezing, chills, and shortness of breath. Central nervous system (CNS) depression may also result. The effects of acute exposure may be delayed in onset up to 12-24 hours. CHRONIC: Repeated exposure above current occupational limits may cause an allergic sensitization of the respiratory tract. This is characterized by an asthma-like response upon re-exposure to the chemical. The symptoms may include coughing, wheezing, shortness of breath and chest tightness, and may be fatal. Central nervous system (CNS) depression may also result; unconsciousness and death may occur in extreme cases.

CARCINOGENICITY: NTP: No IARC Monographs: No OSHA Regulated: No

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Cardiovascular disease, asthma or asthmatic bronchitis, emphysema, allergic disease, dermatitis, chronic respiratory disease, sinusitis, headache and dizziness.

EMERGENCY AND FIRST AID PROCEDURES: EYE CONTACT: Immediately flush eyes with plenty of water, preferably lukewarm. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Have eyes examined and treated by medical personnel. INHALATION: Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is labored, give oxygen. Consult medical personnel. SKIN CONTACT: Wash material off the skin thoroughly with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention. Wash contaminated clothing and decontaminate footwear before reuse. INGESTION: Do not induce vomiting. Give 1-2 glasses of milk or water to drink and refer person to medical personnel. Do not give anything by mouth to an unconscious person.

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wear skin, eye, and respiratory protection during cleanup. Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work area. Prepare a decontamination solution of 2.0% liquid detergent and 3-8% concentrated ammonium hydroxide in water (5-10% sodium carbonate may be substituted for the ammonium hydroxide). Follow the precautions on the supplier's material safety data sheets. All operations should be performed by trained personnel familiar with the hazards of the chemicals used. Treat the spill area with the decontamination solution, using about 10 parts of solution for each part of the spill, and allow it to react for at least 15 minutes. Carbon dioxide will be evolved, leaving insoluble polyureas. Residues from spill cleanup, even when treated as described may continue to be regulated under provisions of RCRA and require storage and disposal as hazardous waste. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.
WASTE DISPOSAL METHOD: Slowly stir the isocyanate waste into the decontamination solution described above using 10 parts of the solution for each part of the isocyanate. Let stand for 48 hours, allowing the evolved carbon dioxide to vent away, residues may still be subject to RCRA storage and disposal requirements. Dispose off in compliance with all relevant local, state, and federal laws and regulations regarding treatment.

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep in cool, dry, ventilated storage area, in closed containers and out of direct sunlight. Store in containers above ground and surrounded by dikes to contain spills or leaks. Sufficient heat or pressure may ignite. Keep containers closed when not in use.

OTHER PRECAUTIONS: Prevent skin and eye contact, observe TLV limitations. Avoid breathing vapors. Workers should shower and change to fresh clothing after each shift. A sensitized individual should not be exposed to the product that caused the sensitization. Air circulation and exhaustion of isocyanate vapors must be maintained until the coatings have fully cured to insure that no potential fire, explosion or health hazard remains. Warning properties (irritation of the eyes, nose and throat or odor) are not adequate to prevent chronic overexposure from inhalation. This product can produce asthmatic sensitization upon either single inhalation exposure to a relatively high concentration or upon repeated inhalation exposure to lower concentrations. Exposure to vapors of heated isocyanates can be extremely dangerous. Employee education and training in safe handling of this material is required under OSHA hazard communication standard. Individuals with existing respiratory disease such as chronic bronchitis, emphysema, or asthma should not be exposed to isocyanates. These individuals should be identified through baseline and annual evaluation and removed from further exposure. Medical examination should include medical history, vital capacity, and forced expiratory volume at one second.

SECTION VIII - CONTROL MEASURES

VENTILATION: If needed, use local exhaust ventilation to keep airborne concentrations below the TLV. Follow guidelines in the ACGIH publication “Industrial Ventilation”.

RESPIRATORY PROTECTION: If airborne concentrations exceed or are expected to exceed the TLV, use MSHA/NIOSH approved positive pressure supplied air respirator with a full-face piece or an air supplied hood. For emergencies, use a positive pressure self-contained breathing apparatus. Air purifying (cartridge type) respirators are not approved for protection against isocyanates.

PROTECTIVE CLOTHING: Gloves determined to be impervious under the conditions of use should be worn always when working with this product. Depending on conditions of use, additional protection may be required such as apron, arm covers, or full body suit. Wash contaminated clothing before wearing. Clothing constructed of butyl rubber, viton, silver shield, Saranex coated Tyvek, as well as some nitrile rubber and polyvinyl alcohol (PVA) coated garments have demonstrated excellent resistance to permeation by isocyanate. Clothing constructed of Teflon, as well as some garments constructed of nitrile rubber, natural rubber and PVA exhibited limited resistance to permeation by isocyanate. Please note that PVA degrades in water. Some clothing constructed of natural rubber or polyethylene exhibited little resistance to permeation by isocyanate. Protective clothing should be selected and used in accordance with "Guidelines for the Selection of Chemical Protective Clothing" published by ACGIH.

EYE PROTECTION: Chemical tight goggles and full-face shield.

OTHER PROTECTIVE EQUIPMENT AND MEASURES: Unhindered access to safety shower and eye wash stations. As a general hygienic practice, wash hands and face after use. Showers and cleaning of clothes are recommended. Follow all label instructions. Educate and train employees in safe use of product.

SECTION IX - REGULATORY INFORMATION

DOT PROPER SHIPPING NAME: Not Regulated.

TOXIC SUBSTANCE CONTROL ACT: All chemicals comprising this product are listed on the TSCA inventory.

USER’S RESPONSIBILITY: A bulletin such as this cannot be expected to cover all possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where, precautions, in addition to those described herein, are required. Any health hazard and safety information herein should be passed on to your customers or employees, as the case may be.

DISCLAIMER: The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole responsibility of the user. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose or any other nature are made hereunder with respect to the information contained herein or the chemical to which the information refers. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.

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FLEXSET Side-B
SECTION I - MANUFACTURER IDENTIFICATION
MANUFACTURER’S NAME: Roklin Systems, Inc. ADDRESS: 20541 Pascal Way, Lake Forest, CA 92630 INFORMATION PHONE: 949-707-6111 EMERGENCY CONTACT: 949-707-6111 DATE REVISED: December 1st. 2008

SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION

SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS

BOILING POINT: >200°C (392°F) SPECIFIC GRAVITY: (H2O=1): 1.044
COATING V.O.C.: N/A VAPOR DENSITY: Heavier than air
EVAPORATION RATE: Slower than ether SOLUBILITY IN WATER: Slight
APPEARANCE & ODOR: Grey liquid, mild aromatic

SECTION IV - FIRE AND EXPLOSION HAZARD DATA

FLASH POINT: 150°C (302°F)
METHOD USED: PMCC
FLAMMABLE LIMITS IN AIR BY VOLUME: Lower: N/E Upper: N/E
EXTINGUISHING MEDIA:Dry chemical, foam, carbon dioxide, halogenated agents. If water is used, use very large quantities of cold water.
SPECIAL FIRE FIGHTING PROCEDURES:Wear NIOSH approved self-contained breathing apparatus in positive pressure mode with full-face piece. Boots, gloves (neoprene), goggles, and full protective clothing are also required.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may rupture due to very high temperature or induced pressure.

SECTION V - REACTIVITY DATA

STABILITY: Stable under normal conditions.

CONDITIONS TO AVOID: Heat, high temperature, open flame, sparks, and moisture. Contact with incompatible materials in a closed system will cause buildup of pressure.

INCOMPATIBILITY (MATERIALS TO AVOID): Isocyanates and strong oxidizers.

HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Organic vapors and other thermal decomposition products.

HAZARDOUS POLYMERIZATION: Will not occur.

SSECTION VI - HEALTH HAZARD DATA

SKIN CONTACT:Frequent and prolonged contact can cause irritation and/or dermatitis.

EYE CONTACT: Can irritate eyes.

SKIN ABSORPTION: Systemically toxic concentrations of this product will probably not be absorbed through human skin.

INGESTION:This material is classified as "Relatively Nontoxic" by ingestion. In humans, irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion, and injury may be severe and possibly fatal in extreme cases.

INHALATION:Vapors can irritate eyes, nose and respiratory passages. Overexposure may induce headaches, dizziness, drowsiness or unconsciousness. Chronic exposures may result in permanent decreases in lung function.

HEALTH HAZARDS: ACUTE:Exposure may cause mucous membrane and respiratory tract irritation, tightness of chest, headache, shortness of breath, and a dry cough. The effects of acute exposure may be delayed in onset up to 12-24 hours. CHRONIC: Repeated exposure above current occupational limits may cause an allergic sensitization of the respiratory tract. This is characterized by an asthma-like response upon re-exposure to the chemical. The symptoms may include coughing, wheezing, shortness of breath and chest tightness, and may be fatal.

CARCINOGENICITY: NTP: No IARC Monographs: No OSHA Regulated: No

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:Cardiovascular disease, asthma or asthmatic bronchitis, allergic disease, chronic respiratory disease, sinusitis, headache, dizziness.

EMERGENCY AND FIRST AID PROCEDURES: EYE CONTACT: Immediately flush eyes with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Have eyes examined and treated by medical personnel. INHALATION: Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If breathing is labored, give oxygen. Consult medical personnel. SKIN CONTACT: Wash material off the skin with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention. Wash contaminated clothing and decontaminate footwear before reuse. INGESTION: Do not induce vomiting. Give 1 or 2 glasses of water to drink and refer person to medical personnel. Never give anything by mouth to an unconscious person.

SSECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:Wear skin, eye, and respiratory protection during cleanup. Soak up material with absorbent and shovel into a chemical waste container. Cover container, but do not seal, and remove from work area. For major spills, call CHEMTREC (Chemical Transportation Emergency Center) at 800-424-9300.

WASTE DISPOSAL METHOD: Empty containers can be disposed of in a normal manner. If A and B residue exists they are to be combined and mixed to create an inert polymerized mass which can then be disposed of in compliance with all relevant local, state, and federal laws and regulations.

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep in cool, dry, ventilated storage area, in closed containers and out of direct sunlight. Keep containers closed when not in use. Do not pressurize containers to empty them.

OTHER PRECAUTIONS: Prevent skin and eye contact.

SSECTION I - MANUFACTURER IDENTIFICATION

PROTECTIVE CLOTHING: Since B side is always used in conjunction with the A side, the same protective clothing standards apply. Nitrile Gloves determined to be impervious under the conditions of use should be worn always when working with the A side product. A Tyvek suit is also recommended. Depending on conditions of use, additional protection may be required such as apron or arm covers. Wash contaminated clothing before wearing.

EYE PROTECTION: Full-face shield/splash guard in case of splashing.

OTHER PROTECTIVE EQUIPMENT AND MEASURES: Unhindered access to safety shower and eye wash stations. As a general hygienic practice, wash hands and face after use. Showers and cleaning of clothes are recommended. Follow all label instructions. Educate and train employees in safe use of product.

SSECTION IX - REGULATORY INFORMATION

DOT PROPER SHIPPING NAME: Not Regulated.

IATA PROPER SHIPPING NAME: Not Regulated.

IMO PROPER SHIPPING NAME: Not Regulated.

STATE REGULATIONS: CALIFORNIA - As per requirements of the Safe Drinking Water & Toxic Enforcement Act of CA, USA 1985 (proposition 65), the public is warned that materials used in this product may create an exposure to chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm. This warning required by Section 25249.6 of the California Health and Safety Code.

TOXIC SUBSTANCE CONTROL ACT: All chemicals comprising this product are listed on the TSCA inventory.

USER’S RESPONSIBILITY: A bulletin such as this cannot be expected to cover all possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where, precautions, in addition to those described herein, are required. Any health hazard and safety information herein should be passed on to your customers or employees, as the case may be.

DISCLAIMER:The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. All chemicals may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. Final determination of suitability of the chemical is the sole responsibility of the user. No representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose or any other nature are made hereunder with respect to the information contained herein or the chemical to which the information refers. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.